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Issue 68, 2013
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Mechano-isomerization of azobenzene

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Abstract

We show that ultrasound-induced mechanical force isomerizes an azobenzene centered within a poly(methyl acrylate) polymer from cis to trans configuration without cleaving the azo bond. The isomerization rate was not altered by the polarity of the solvent indicating that the isomerization occurs through a non-polar, inversion transition state.

Graphical abstract: Mechano-isomerization of azobenzene

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Article information


Submitted
20 May 2013
Accepted
25 Jun 2013
First published
26 Jun 2013

Chem. Commun., 2013,49, 7519-7521
Article type
Communication

Mechano-isomerization of azobenzene

S. K. Surampudi, H. R. Patel, G. Nagarjuna and D. Venkataraman, Chem. Commun., 2013, 49, 7519
DOI: 10.1039/C3CC43797C

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