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Issue 88, 2013
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A C3-symmetric chiroptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation

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Abstract

Propeller-shaped dynamic helicity was generated in a hexakis(phenylethynyl)benzene framework that preferred a particular sense to afford a strong CD signal, which was realized by the cooperative transmission of point chiralities upon complexation with a chiral guest through a threefold binding site presented by a syn-formed terephthalamide.

Graphical abstract: A C3-symmetric chiroptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation

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Article information


Submitted
13 May 2013
Accepted
10 Jun 2013
First published
11 Jun 2013

Chem. Commun., 2013,49, 10352-10354
Article type
Communication

A C3-symmetric chiroptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation

R. Katoono, H. Kawai, M. Ohkita, K. Fujiwara and T. Suzuki, Chem. Commun., 2013, 49, 10352
DOI: 10.1039/C3CC43571G

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