Issue 68, 2013

Halogen bonding in fluorine: experimental charge density study on intermolecular F⋯F and F⋯S donor–acceptor contacts

Abstract

The enigmatic type II C–F⋯F–C and C–F⋯S–C interactions in pentafluorophenyl 2,2′-bithiazole are shown to be realistic “σ-hole” interactions based on high resolution X-ray charge density analysis.

Graphical abstract: Halogen bonding in fluorine: experimental charge density study on intermolecular F⋯F and F⋯S donor–acceptor contacts

Supplementary files

Article information

Article type
Communication
Submitted
10 May 2013
Accepted
01 Jul 2013
First published
01 Jul 2013

Chem. Commun., 2013,49, 7558-7560

Halogen bonding in fluorine: experimental charge density study on intermolecular F⋯F and F⋯S donor–acceptor contacts

M. S. Pavan, K. Durga Prasad and T. N. Guru Row, Chem. Commun., 2013, 49, 7558 DOI: 10.1039/C3CC43513J

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