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Issue 60, 2013
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Storable palladacycles for selective functionalization of alkyne-containing proteins

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Abstract

We report the facile preparation of palladacycles as storable arylpalladium(II) reagents from acetanilides via cyclopalladation. The palladacycles exhibit good stability in PBS buffer and are capable of functionalizing a metabolically encoded HPG-containing protein, thus providing a new type of biocompatible organometallic reagent for selectively functionalizing the alkyne-encoded proteins.

Graphical abstract: Storable palladacycles for selective functionalization of alkyne-containing proteins

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Publication details

The article was received on 10 May 2013, accepted on 03 Jun 2013 and first published on 03 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43479F
Citation: Chem. Commun., 2013,49, 6809-6811

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    Storable palladacycles for selective functionalization of alkyne-containing proteins

    G. Cheng, R. K. V. Lim, N. Li and Q. Lin, Chem. Commun., 2013, 49, 6809
    DOI: 10.1039/C3CC43479F

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