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Issue 71, 2013
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Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions

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Abstract

We report a synthetic nickel complex containing proton relays, [Ni(PPh2NC6H4OH2)2](BF4)2 (PPh2NC6H4OH2 = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclo-octane), that catalyzes the production of H2 in aqueous acetonitrile with turnover frequencies of 750–170 000 s−1 at experimentally determined overpotentials of 310–470 mV.

Graphical abstract: Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions

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Publication details

The article was received on 30 Apr 2013, accepted on 29 May 2013 and first published on 30 May 2013


Article type: Communication
DOI: 10.1039/C3CC43203C
Citation: Chem. Commun., 2013,49, 7767-7769

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    Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions

    W. A. Hoffert, J. A. S. Roberts, R. Morris Bullock and M. L. Helm, Chem. Commun., 2013, 49, 7767
    DOI: 10.1039/C3CC43203C

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