Rigid organic nanotubes were prepared from six-membered phenylene-butadiynylene macrocycles through topochemical polymerization in the xerogel state. All six butadiyne units underwent polymerization, thus creating rigid nanotubes with six polydiacetylene chains lying parallel, one relative to each other.
S. Rondeau-Gagné, J. R. Néabo, M. Desroches, I. Levesque, M. Daigle, K. Cantin and J. Morin, Chem. Commun., 2013, 49, 9546 DOI: 10.1039/C3CC43177K
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