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Issue 51, 2013
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Slothful gelation of a dipolar building block by “top-down” morphology transition from microparticles to nanofibres

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Abstract

An amide-functionalized dipolar building block showed spontaneous self-assembly to micro-particles predominately by H-bonding. Possibly due to inefficient dipolar interaction, it gradually adopted an alternate mode of assembly by anti-parallel dimerization and H-bonding in orthogonal directions leading to a strikingly different nano-fibrillar morphology resulting in unusually slow gelation after 80 h.

Graphical abstract: Slothful gelation of a dipolar building block by “top-down” morphology transition from microparticles to nanofibres

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Article information


Submitted
16 Apr 2013
Accepted
03 May 2013
First published
07 May 2013

Chem. Commun., 2013,49, 5757-5759
Article type
Communication

Slothful gelation of a dipolar building block by “top-down” morphology transition from microparticles to nanofibres

A. Das, B. Maity, D. Koley and S. Ghosh, Chem. Commun., 2013, 49, 5757
DOI: 10.1039/C3CC42808G

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