Issue 56, 2013
From the journal:

Chemical Communications

Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: structural insights and solvent effects†

David J. Harding,*a   Wasinee Phonsri,a   Phimphaka Harding,a   Ian A. Gass,b   Keith S. Murray,b   Boujemaa Moubaraki,b   John D. Cashion,c   Lujia Liud  and  Shane G. Telferd  

* Corresponding authors

a Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat, Thailand
E-mail: hdavid@wu.ac.th
Tel: +66-75-672094

b Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, Australia

c Department of Physics, Monash University, Melbourne, Victoria, Australia

d MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

Graphical abstract: Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: structural insights and solvent effects

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Article information

DOI
https://doi.org/10.1039/C3CC42125B
Article type
Communication
Submitted
24 Mar 2013
Accepted
04 Jun 2013
First published
04 Jun 2013

Chem. Commun., 2013,49, 6340-6342

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Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

D. J. Harding, W. Phonsri, P. Harding, I. A. Gass, K. S. Murray, B. Moubaraki, J. D. Cashion, L. Liu and S. G. Telfer, Chem. Commun., 2013, 49, 6340 DOI: 10.1039/C3CC42125B

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