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A novel and facile method is developed to prepare an Ag@AgCl film which exhibits high photocatalytic activity under visible light irradiation. In addition, it can also be used to fabricate a photodetector that possesses a fast response time and good photocurrent reproducibility.

Graphical abstract: Facile synthesis of a free-standing Ag@AgCl film for a high performance photocatalyst and photodetector

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