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Issue 48, 2013
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Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate

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Abstract

A transition-metal-free direct oxidative trifluoromethylation of unsymmetrical biaryls has been achieved by the simple combination of trifluoromethanesulfinate and phenyliodine bis(trifluoroacetate). The trifluoromethylation is selectively observed in the electron-rich arenes.

Graphical abstract: Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate

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Article information


Submitted
05 Mar 2013
Accepted
23 Apr 2013
First published
24 Apr 2013

Chem. Commun., 2013,49, 5510-5512
Article type
Communication

Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate

Y. Yang, K. Iwamoto, E. Tokunaga and N. Shibata, Chem. Commun., 2013, 49, 5510
DOI: 10.1039/C3CC41667D

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