Issue 40, 2013
From the journal:

Chemical Communications

An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water†

Maya Chatterjee,*a   Takayuki Ishizaka,a   Akira Suzukia  and  Hajime Kawanami*a  

* Corresponding authors

a Research Center for Compact Chemical System, AIST, Tohoku, 4-2-1 Nigatake, Miyagino-ku Sendai, Japan
E-mail: c-maya@aist.go.jp, h-kawanami@aist.go.jp
Fax: +81 22 237 5388
Tel: +81 22 237 5213

Abstract

A simple and highly efficient Rh/C catalyzed route for the cleavage of the C–O bond of aromatic ether at 80 °C in the presence of 0.5 MPa of H2 in the scCO2–water medium is reported; CO2 pressure and water play a key role under the tested conditions.

Graphical abstract: An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water

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Article information

DOI
https://doi.org/10.1039/C3CC41522H
Article type
Communication
Submitted
28 Feb 2013
Accepted
28 Mar 2013
First published
28 Mar 2013

Chem. Commun., 2013,49, 4567-4569

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An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water

M. Chatterjee, T. Ishizaka, A. Suzuki and H. Kawanami, Chem. Commun., 2013, 49, 4567 DOI: 10.1039/C3CC41522H

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