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Issue 56, 2013
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Structural transition and unusually strong antiferromagnetic superexchange coupling in perovskite KAgF3

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Abstract

High-purity samples of potassium trifluoroargentate(II), KAgF3, have been obtained via a novel synthetic pathway. This compound is found to exhibit an order–disorder phase transition around 230 K. Susceptibility measurements indicate that KAgF3 exhibits strong antiferromagnetic (AFM) coupling reminiscent of that found in copper(II) oxides.

Graphical abstract: Structural transition and unusually strong antiferromagnetic superexchange coupling in perovskite KAgF3

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Article information


Submitted
27 Feb 2013
Accepted
08 Apr 2013
First published
08 Apr 2013

Chem. Commun., 2013,49, 6262-6264
Article type
Communication

Structural transition and unusually strong antiferromagnetic superexchange coupling in perovskite KAgF3

D. Kurzydłowski, Z. Mazej, Z. Jagličić, Y. Filinchuk and W. Grochala, Chem. Commun., 2013, 49, 6262
DOI: 10.1039/C3CC41521J

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