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Issue 45, 2013
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Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(ii)

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Abstract

cis-[(Cy3P)2Pt{B(OMe)2}2] (1) was obtained in quantitative yield and fully characterised. The thermal stability of 1 was investigated in solution using multinuclear NMR spectroscopy revealing a hitherto unknown temperature-dependent equilibrium between 1 and the corresponding starting materials [Pt(PCy3)2] and free B2(OMe)4.

Graphical abstract: Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(ii)

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Supplementary files

Article information


Submitted
25 Feb 2013
Accepted
08 Apr 2013
First published
08 Apr 2013

Chem. Commun., 2013,49, 5216-5218
Article type
Communication

Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

H. Braunschweig and A. Damme, Chem. Commun., 2013, 49, 5216
DOI: 10.1039/C3CC41444B

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