Jump to main content
Jump to site search

Issue 45, 2013
Previous Article Next Article

Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

Author affiliations

Abstract

cis-[(Cy3P)2Pt{B(OMe)2}2] (1) was obtained in quantitative yield and fully characterised. The thermal stability of 1 was investigated in solution using multinuclear NMR spectroscopy revealing a hitherto unknown temperature-dependent equilibrium between 1 and the corresponding starting materials [Pt(PCy3)2] and free B2(OMe)4.

Graphical abstract: Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(ii)

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Feb 2013, accepted on 08 Apr 2013 and first published on 08 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41444B
Citation: Chem. Commun., 2013,49, 5216-5218
  •   Request permissions

    Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

    H. Braunschweig and A. Damme, Chem. Commun., 2013, 49, 5216
    DOI: 10.1039/C3CC41444B

Search articles by author

Spotlight

Advertisements