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Issue 42, 2013
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Synthesis of optically pure [60]fullerene e,e,e-tris adducts

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Abstract

The reaction of readily available optically active Si-tethered tris(malonates) with C60 gave easily separable diastereoisomers differing by the absolute configuration of the inherently chiral addition pattern on the fullerene core. The absolute configuration of the e,e,e addition pattern has been unambiguously determined using X-ray crystal structure analysis.

Graphical abstract: Synthesis of optically pure [60]fullerene e,e,e-tris adducts

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Article information


Submitted
23 Feb 2013
Accepted
08 Apr 2013
First published
19 Apr 2013

Chem. Commun., 2013,49, 4752-4754
Article type
Communication

Synthesis of optically pure [60]fullerene e,e,e-tris adducts

S. Guerra, F. Schillinger, D. Sigwalt, M. Holler and J. Nierengarten, Chem. Commun., 2013, 49, 4752
DOI: 10.1039/C3CC41409D

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