Issue 37, 2013
From the journal:

Chemical Communications

Formation and characterization of HUF and DUF in solid argon†

Thomas Vent-Schmidt,a   Rodney Dale Hunt,b   Lester Andrews*ac  and  Sebastian Riedel*a  

* Corresponding authors

a Albert-Ludwigs Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg, Germany
E-mail: sriedel@psichem.de
Web: www.psichem.de
Fax: +49-7612036001
Tel: +49-7612038717

b Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6223, USA
E-mail: huntrd@ornl.gov

c University of Virginia, Department of Chemistry, Charlottesville, VA, USA
E-mail: lsa@virginia.edu

Abstract

Reactions of laser-ablated U atoms with HF and DF in condensing and solid rare gas produce HUF and DUF as the major new products based on close agreement between observed and calculated vibrational frequencies and deuterium shifts for U–H and U–F stretching modes at 1383 and 544 cm−1, respectively.

Graphical abstract: Formation and characterization of HUF and DUF in solid argon

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Article information

DOI
https://doi.org/10.1039/C3CC41379A
Article type
Communication
Submitted
22 Feb 2013
Accepted
19 Mar 2013
First published
19 Mar 2013

Chem. Commun., 2013,49, 3863-3865

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Formation and characterization of HUF and DUF in solid argon

T. Vent-Schmidt, R. D. Hunt, L. Andrews and S. Riedel, Chem. Commun., 2013, 49, 3863 DOI: 10.1039/C3CC41379A

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