Issue 41, 2013
From the journal:

Chemical Communications

[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources†

Wenbo Xiao,a   Jinhu Wei,a   Cong-Ying Zhou*ab  and  Chi-Ming Che*ab  

* Corresponding authors

a Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China
E-mail: cmche@hku.hk, cyzhou@hku.hk
Fax: +85228571586
Tel: +85228592154

b HKU Shenzhen Institute of Research & Innovation, Shenzhen, China

Abstract

[RuIV(F20-TPP)Cl2][H2(F20-TPP) = meso-tetrakis(pentafluorophenyl)porphyrin] is an active catalyst for both inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons in good to high product yields using phosphoryl azides as nitrene sources.

Graphical abstract: [RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

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Article information

DOI
https://doi.org/10.1039/C3CC41110A
Article type
Communication
Submitted
09 Feb 2013
Accepted
28 Mar 2013
First published
03 Apr 2013

Chem. Commun., 2013,49, 4619-4621

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[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

W. Xiao, J. Wei, C. Zhou and C. Che, Chem. Commun., 2013, 49, 4619 DOI: 10.1039/C3CC41110A

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