Issue 41, 2013
From the journal:

Chemical Communications

Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group†

Li Yan Chan,a   Sunggak Kim,*a   Taekyu Ryub  and  Phil Ho Lee*b  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
E-mail: sgkim@ntu.edu.sg

b Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea
E-mail: phlee@kangwon.ac.kr

Abstract

A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C–H activation.

Graphical abstract: Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

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Article information

DOI
https://doi.org/10.1039/C3CC41107A
Article type
Communication
Submitted
09 Feb 2013
Accepted
02 Apr 2013
First published
11 Apr 2013

Chem. Commun., 2013,49, 4682-4684

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Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

L. Y. Chan, S. Kim, T. Ryu and P. H. Lee, Chem. Commun., 2013, 49, 4682 DOI: 10.1039/C3CC41107A

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