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Issue 29, 2013
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Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111

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Abstract

We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

Graphical abstract: Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111

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Article information


Submitted
31 Jan 2013
Accepted
20 Feb 2013
First published
21 Feb 2013

Chem. Commun., 2013,49, 2992-2994
Article type
Communication

Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111

Y. Peng, G. Srinivas, C. E. Wilmer, I. Eryazici, R. Q. Snurr, J. T. Hupp, T. Yildirim and O. K. Farha, Chem. Commun., 2013, 49, 2992
DOI: 10.1039/C3CC40819A

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