Issue 31, 2013
From the journal:

Chemical Communications

Chemically crosslinked isoreticular metal–organic frameworks†

Corinne A. Allen,a   Jake A. Boissonnault,a   Jordi Cirera,a   Ryan Gulland,a   Francesco Paesania  and  Seth M. Cohen*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, USA 92093
E-mail: scohen@ucsd.edu

Abstract

Herein we report the synthesis of canonical isoreticular metal–organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.

Graphical abstract: Chemically crosslinked isoreticular metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C3CC40635K
Article type
Communication
Submitted
24 Jan 2013
Accepted
05 Mar 2013
First published
06 Mar 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 3200-3202

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Chemically crosslinked isoreticular metal–organic frameworks

C. A. Allen, J. A. Boissonnault, J. Cirera, R. Gulland, F. Paesani and S. M. Cohen, Chem. Commun., 2013, 49, 3200 DOI: 10.1039/C3CC40635K

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