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Issue 23, 2013
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Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a ‘semi’-hydrated chelate

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Abstract

Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.

Graphical abstract: Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a ‘semi’-hydrated chelate

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Publication details

The article was received on 09 Dec 2012, accepted on 04 Feb 2013 and first published on 12 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38814J
Chem. Commun., 2013,49, 2320-2322

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    Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a ‘semi’-hydrated chelate

    K. M. Payne, E. J. Valente, S. Aime, M. Botta and M. Woods, Chem. Commun., 2013, 49, 2320
    DOI: 10.1039/C3CC38814J

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