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Issue 27, 2013
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A four-coordinate thionitrosyl complex of vanadium

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Addition of elemental sulfur to the vanadium nitride [(nacnac)V[triple bond, length as m-dash]N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended π-resonance across the VNS moiety.

Graphical abstract: A four-coordinate thionitrosyl complex of vanadium

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The article was received on 07 Dec 2012, accepted on 15 Feb 2013 and first published on 18 Feb 2013

Article type: Communication
DOI: 10.1039/C3CC38799B
Chem. Commun., 2013,49, 2768-2770

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    A four-coordinate thionitrosyl complex of vanadium

    B. L. Tran, R. Thompson, S. Ghosh, X. Gao, C. Chen, M. Baik and D. J. Mindiola, Chem. Commun., 2013, 49, 2768
    DOI: 10.1039/C3CC38799B

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