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Issue 27, 2013
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Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Abstract

The bicyclic diboron species 1 was generated with high selectivity by a combination of boron carbon bond formation and hydrogen iodide elimination events. The nature of the boracycle 1 was evaluated using X-ray diffraction, NMR spectroscopy and density functional theory calculations.

Graphical abstract: Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Article information


Submitted
07 Dec 2012
Accepted
14 Feb 2013
First published
18 Feb 2013

Chem. Commun., 2013,49, 2774-2776
Article type
Communication

Synthesis of a bicyclic diborane by selective boron carbon bond formation

H. Braunschweig, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2774
DOI: 10.1039/C3CC38789E

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