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Issue 27, 2013
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Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Abstract

The bicyclic diboron species 1 was generated with high selectivity by a combination of boron carbon bond formation and hydrogen iodide elimination events. The nature of the boracycle 1 was evaluated using X-ray diffraction, NMR spectroscopy and density functional theory calculations.

Graphical abstract: Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Publication details

The article was received on 07 Dec 2012, accepted on 14 Feb 2013 and first published on 18 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38789E
Citation: Chem. Commun., 2013,49, 2774-2776
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    Synthesis of a bicyclic diborane by selective boron carbon bond formation

    H. Braunschweig, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2774
    DOI: 10.1039/C3CC38789E

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