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Issue 24, 2013
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A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

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Abstract

A novel μ2-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear 1, in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.

Graphical abstract: A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

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Article information


Submitted
04 Dec 2012
Accepted
04 Feb 2013
First published
06 Feb 2013

Chem. Commun., 2013,49, 2439-2441
Article type
Communication

A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

H. Braunschweig, R. Bertermann, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2439
DOI: 10.1039/C3CC38686D

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