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Issue 24, 2013
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A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

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Abstract

A novel μ2-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear 1, in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.

Graphical abstract: A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

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Publication details

The article was received on 04 Dec 2012, accepted on 04 Feb 2013 and first published on 06 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38686D
Citation: Chem. Commun., 2013,49, 2439-2441
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    A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

    H. Braunschweig, R. Bertermann, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2439
    DOI: 10.1039/C3CC38686D

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