Issue 22, 2013
From the journal:

Chemical Communications

An inorganic–organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission†

Huabin Zhang,ab   Ping Lin,a   Xiaochen Shan,ab   Fenglei Du,ab   Qipeng Liab  and  Shaowu Du*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: swdu@fjirsm.ac.cn
Fax: +86-591-83709470

b Graduate University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

The first example of an inorganic–organic composite framework with a 3D inorganic Cd–O–M (M = Cd, Rb) connectivity, featuring a unique {Cd7Rb}n helix and nanoscale {Cd16Rb4} and {Cd18Rb2} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.

Graphical abstract: An inorganic–organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission

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Article information

DOI
https://doi.org/10.1039/C3CC38655D
Article type
Communication
Submitted
03 Dec 2012
Accepted
29 Jan 2013
First published
30 Jan 2013

Chem. Commun., 2013,49, 2231-2233

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An inorganic–organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission

H. Zhang, P. Lin, X. Shan, F. Du, Q. Li and S. Du, Chem. Commun., 2013, 49, 2231 DOI: 10.1039/C3CC38655D

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