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Issue 16, 2013
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Achiral endohedral functionality provides stereochemical control in Fe(ii)-based self-assemblies

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Abstract

Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.

Graphical abstract: Achiral endohedral functionality provides stereochemical control in Fe(ii)-based self-assemblies

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Article information


Submitted
31 Oct 2012
Accepted
05 Jan 2013
First published
08 Jan 2013

Chem. Commun., 2013,49, 1627-1629
Article type
Communication

Achiral endohedral functionality provides stereochemical control in Fe(II)-based self-assemblies

M. C. Young, A. M. Johnson, A. S. Gamboa and R. J. Hooley, Chem. Commun., 2013, 49, 1627
DOI: 10.1039/C3CC37912D

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