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Issue 16, 2013
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Achiral endohedral functionality provides stereochemical control in Fe(ii)-based self-assemblies

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Abstract

Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.

Graphical abstract: Achiral endohedral functionality provides stereochemical control in Fe(ii)-based self-assemblies

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Publication details

The article was received on 31 Oct 2012, accepted on 05 Jan 2013 and first published on 08 Jan 2013


Article type: Communication
DOI: 10.1039/C3CC37912D
Chem. Commun., 2013,49, 1627-1629

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    Achiral endohedral functionality provides stereochemical control in Fe(II)-based self-assemblies

    M. C. Young, A. M. Johnson, A. S. Gamboa and R. J. Hooley, Chem. Commun., 2013, 49, 1627
    DOI: 10.1039/C3CC37912D

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