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Issue 13, 2013
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Dynamic topomerization of Cu(i)-complexed pseudorotaxanes

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Abstract

Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.

Graphical abstract: Dynamic topomerization of Cu(i)-complexed pseudorotaxanes

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Supplementary files

Article information


Submitted
24 Oct 2012
Accepted
28 Nov 2012
First published
29 Nov 2012

Chem. Commun., 2013,49, 1261-1263
Article type
Communication

Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

M. Mohankumar, M. Holler, M. Schmitt, J. Sauvage and J. Nierengarten, Chem. Commun., 2013, 49, 1261
DOI: 10.1039/C2CC37724A

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