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Issue 13, 2013
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Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

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Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.

Graphical abstract: Dynamic topomerization of Cu(i)-complexed pseudorotaxanes

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The article was received on 24 Oct 2012, accepted on 28 Nov 2012 and first published on 29 Nov 2012

Article type: Communication
DOI: 10.1039/C2CC37724A
Citation: Chem. Commun., 2013,49, 1261-1263
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    Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

    M. Mohankumar, M. Holler, M. Schmitt, J. Sauvage and J. Nierengarten, Chem. Commun., 2013, 49, 1261
    DOI: 10.1039/C2CC37724A

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