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By the reaction of TBA4H4[γ-SiW10O36] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6]4+ cluster, TBA8[Ag6(γ-H2SiW10O36)2]·5H2O, could be synthesized, and the molecular structure was determined.

Graphical abstract: A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

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