Jump to main content
Jump to site search

Issue 39, 2013
Previous Article Next Article

Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

Author affiliations

Abstract

π-Coordination of pyrrole or indole which lack a chelating functionality to a dinuclear PdI–PdI center is revealed. The dinuclear sandwich PdI–PdI complexes of pyrrole, N-methylpyrrole, or indole were synthesized and structurally characterized by X-ray crystallographic analysis. Indole employs the carbons of the six-membered ring in bridging π-coordination to a PdI–PdI center.

Graphical abstract: Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Oct 2012, accepted on 03 Dec 2012 and first published on 20 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC37554K
Chem. Commun., 2013,49, 4310-4312

  •   Request permissions

    Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

    T. Murahashi, S. Kimura, K. Takase, S. Ogoshi and K. Yamamoto, Chem. Commun., 2013, 49, 4310
    DOI: 10.1039/C2CC37554K

Search articles by author

Spotlight

Advertisements