Issue 1, 2013
From the journal:

Chemical Communications

Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds†

Mengtao Ma,‡a   Anastas Sidiropoulos,a   Lalrempuia Ralte,a   Andreas Stasch*a  and  Cameron Jones*a  

* Corresponding authors

a School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, Australia
E-mail: cameron.jones@monash.edu, andreas.stasch@monash.edu
Fax: +61-3-9905-4597
Tel: +61-3-9902-0391

Abstract

Reactions of [Pt(PCy3)2] (Cy = cyclohexyl) with group 12 metal dihalides have afforded the novel metal only Lewis pair (MOLP) complexes, [(Cy3P)2Pt→MX2] (M = Zn or Cd, X = Br or I), or the oxidative addition product, trans-[(Cy3P)2(I)PtHgI]. The zinc complex represents the first MOLP to contain an unsupported Pt→Zn linkage.

Graphical abstract: Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

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Article information

DOI
https://doi.org/10.1039/C2CC37442K
Article type
Communication
Submitted
12 Oct 2012
Accepted
02 Nov 2012
First published
05 Nov 2012

Chem. Commun., 2013,49, 48-50

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Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

M. Ma, A. Sidiropoulos, L. Ralte, A. Stasch and C. Jones, Chem. Commun., 2013, 49, 48 DOI: 10.1039/C2CC37442K

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