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Issue 39, 2013
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Formal γ-alkynylation of ketonesvia Pd-catalyzed C–C cleavage

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Abstract

A formal γ-alkynylation of ketones via Pd-catalyzed C–C bond-cleavage is presented. The method allows for the coupling of tert-cyclobutanols and bromoacetylenes, giving access to versatile alkynes that are beyond reach otherwise.

Graphical abstract: Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

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Publication details

The article was received on 05 Oct 2012, accepted on 29 Oct 2012 and first published on 30 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC37281A
Chem. Commun., 2013,49, 4286-4288

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    Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

    A. Ziadi, A. Correa and R. Martin, Chem. Commun., 2013, 49, 4286
    DOI: 10.1039/C2CC37281A

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