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Issue 36, 2013
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Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

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Abstract

Reaction of 4,6-dihydrazinopyrimidines with 2,6-dicarbonylpyridines produces, under metal-free or template conditions, a new class of [3 + 3] macrocycles with 15 Nsp2 donor atoms. Nine Nsp2 atoms are on the external circumference of the macrocycle. The macrocycle can bind metal ions and produce trinuclear complexes along with the motion of the nine outer Nsp2 atoms to inner positions (a motion of inversion of the macrocycle).

Graphical abstract: Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

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Article information


Submitted
04 Oct 2012
Accepted
14 Dec 2012
First published
02 Apr 2013

Chem. Commun., 2013,49, 3784-3786
Article type
Communication

Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

A. Stadler, J. Jiang, H. Wang and C. Bailly, Chem. Commun., 2013, 49, 3784
DOI: 10.1039/C2CC37260F

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