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Issue 39, 2013
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The tandem intermolecular hydroalkoxylation/claisen rearrangement

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Abstract

The Au(I)-catalyzed intermolecular hydroalkoxylation of alkynes with allylic alcohols to provide allyl vinyl ethers that subsequently undergo Claisen rearrangement is reported. This new cascade reaction strategy facilitates the direct formation of γ,δ-unsaturated ketones from simple starting materials in a single step.

Graphical abstract: The tandem intermolecular hydroalkoxylation/claisen rearrangement

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Publication details

The article was received on 01 Oct 2012, accepted on 05 Nov 2012 and first published on 06 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37166A
Chem. Commun., 2013,49, 4157-4159

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    The tandem intermolecular hydroalkoxylation/claisen rearrangement

    J. M. Ketcham, B. Biannic and A. Aponick, Chem. Commun., 2013, 49, 4157
    DOI: 10.1039/C2CC37166A

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