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Issue 39, 2013
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Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

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Abstract

A novel mixed-valence Cu(I)–Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3ICuIIBr3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.

Graphical abstract: Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

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Publication details

The article was received on 01 Oct 2012, accepted on 10 Dec 2012 and first published on 19 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC37137E
Chem. Commun., 2013,49, 4316-4318

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    Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

    T. Okubo, H. Anma, N. Tanaka, K. Himoto, S. Seki, A. Saeki, M. Maekawa and T. Kuroda-Sowa, Chem. Commun., 2013, 49, 4316
    DOI: 10.1039/C2CC37137E

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