Issue 2, 2013
From the journal:

Chemical Communications

Relaxations in heterolanthanide dinuclear single-molecule magnets†

Ji-Dong Leng,a   Jun-Liang Liu,a   Yan-Zhen Zheng,*b   Liviu Ungur,c   Liviu F. Chibotaru,*c   Fu-Sheng Guoa  and  Ming-Liang Tong*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: tongml@mail.sysu.edu.cn

b Center for Applied Chemical Research, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710054, China

c Division of Quantum and Physical Chemistry, Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

Abstract

A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

Graphical abstract: Relaxations in heterolanthanide dinuclear single-molecule magnets

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Article information

DOI
https://doi.org/10.1039/C2CC37036K
Article type
Communication
Submitted
28 Sep 2012
Accepted
08 Nov 2012
First published
08 Nov 2012

Chem. Commun., 2013,49, 158-160

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Relaxations in heterolanthanide dinuclear single-molecule magnets

J. Leng, J. Liu, Y. Zheng, L. Ungur, L. F. Chibotaru, F. Guo and M. Tong, Chem. Commun., 2013, 49, 158 DOI: 10.1039/C2CC37036K

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