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Issue 2, 2013
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Relaxations in heterolanthanide dinuclear single-molecule magnets

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Abstract

A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

Graphical abstract: Relaxations in heterolanthanide dinuclear single-molecule magnets

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Supplementary files

Publication details

The article was received on 28 Sep 2012, accepted on 08 Nov 2012 and first published on 08 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37036K
Citation: Chem. Commun., 2013,49, 158-160

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    Relaxations in heterolanthanide dinuclear single-molecule magnets

    J. Leng, J. Liu, Y. Zheng, L. Ungur, L. F. Chibotaru, F. Guo and M. Tong, Chem. Commun., 2013, 49, 158
    DOI: 10.1039/C2CC37036K

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