Issue 39, 2013
From the journal:

Chemical Communications

Oxo-sulfido- and oxo-selenido-molybdenum(vi) complexes possessing a dithioleneligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation†‡

Hideki Sugimoto,*a   Susumu Tatemoto,a   Kazuo Toyota,*b   Kenji Ashikari,a   Minoru Kubo,b   Takashi Ogurab  and  Shinobu Itoh*a  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Japan
E-mail: sugimoto@mls.eng.osaka-u.ac.jp

b Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sumiyoshi-ku, Japan
E-mail: toyota@sci.osaka-cu.ac.jp

c Picobiology Institute, Graduate School of Life Science, University of Hyogo, 30201 Kouto, Ako-gun, Japan

Abstract

Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.

Graphical abstract: Oxo-sulfido- and oxo-selenido-molybdenum(vi) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

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Article information

DOI
https://doi.org/10.1039/C2CC35345H
Article type
Communication
Submitted
24 Jul 2012
Accepted
08 Oct 2012
First published
08 Oct 2012

Chem. Commun., 2013,49, 4358-4360

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Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

H. Sugimoto, S. Tatemoto, K. Toyota, K. Ashikari, M. Kubo, T. Ogura and S. Itoh, Chem. Commun., 2013, 49, 4358 DOI: 10.1039/C2CC35345H

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