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Issue 48, 2013
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A low temperature TiP2O7 polymorph exhibiting reversible insertion of lithium and sodium ions

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Abstract

A new TiP2O7 form has been prepared by low temperature synthesis, which does not exhibit the superstructure reported when TiP2O7 is prepared via a conventional ceramic route. This LT-TiP2O7 polymorph presents linear P2O7 pyrophosphate groups, connected through a pivotal oxygen which ensure the flexibility of the structure. Therefore it can reversibly take up both Li and Na ions, contrary to the high temperature polymorph that can only take up Li.

Graphical abstract: A low temperature TiP2O7 polymorph exhibiting reversible insertion of lithium and sodium ions

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Article information


Submitted
18 Sep 2013
Accepted
18 Oct 2013
First published
22 Oct 2013

J. Mater. Chem. A, 2013,1, 15284-15291
Article type
Paper

A low temperature TiP2O7 polymorph exhibiting reversible insertion of lithium and sodium ions

P. Senguttuvan, G. Rousse, J. Oró-Solé, J. M. Tarascon and M. R. Palacín, J. Mater. Chem. A, 2013, 1, 15284
DOI: 10.1039/C3TA13756B

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