Design principles for superamphiphobic surfaces
Abstract
To predict the properties of superamphiphobic layers we analyzed the wetting of a square and a hexagonal array of vertical pillars composed of spheres (radius R) partially sintered together. Apparent contact angles above 150° are obtained by pinning of a non-polar liquid surface at the underside of the top sphere resulting in a Fakir or Cassie state. Analytical equations are derived for the impalement pressure in the limiting case A0 ≫ R2, where A0 is the area of the regular unit cell containing a single pillar. The case of close pillars is investigated numerically. By balancing forces at the rim of a drop, we calculate the apparent receding contact angle. To describe drag