Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 4, 2013
Previous Article Next Article

Single molecule magnetism in a family of mononuclear β-diketonate lanthanide(iii) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

Author affiliations

Abstract

The use of an amino-pyridyl substituted β-diketone, N-(2-pyridyl)-ketoacetamide (paaH), has allowed for the isolation of two new families of isostructural mononuclear lanthanide complexes with general formulae: [Ln(paaH*)2(H2O)4][Cl]3·2H2O (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5) and Y (6)) and [Ln(paaH*)2(NO3)2(MeOH)][NO3] (Ln = Tb (7), Dy (8), Ho (9) and Er (10)). The dysprosium members of each family (3 and 8) show interesting slow magnetic relaxation features. Compound 3 displays Single Molecule Magnet (SMM) behaviour in zero DC field with an energy barrier to thermal relaxation of Ea = 177(4) K (123(2) cm−1) with τ0 = 2.5(8) × 10−7 s, while compound 8 shows slow relaxation of the magnetization under an optimum DC field of 0.2 T with an energy barrier to thermal relaxation of Ea = 64 K (44 cm−1) with τ0 = 6.2 × 10−7 s. Ab initio multiconfigurational calculations of the Complete Active Space type have been employed to elucidate the electronic and magnetic structure of the low-lying energy levels of compounds 2–5 and 8. The orientation of the anisotropic magnetic moments for compounds 2–5 are rationalized using a clear and succinct, chemically intuitive method based on the electrostatic repulsion of the aspherical electron density distributions of the lanthanides.

Graphical abstract: Single molecule magnetism in a family of mononuclear β-diketonate lanthanide(iii) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

Back to tab navigation

Supplementary files

Article information


Submitted
21 Dec 2012
Accepted
30 Jan 2013
First published
31 Jan 2013

Chem. Sci., 2013,4, 1719-1730
Article type
Edge Article

Single molecule magnetism in a family of mononuclear β-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

N. F. Chilton, S. K. Langley, B. Moubaraki, A. Soncini, S. R. Batten and K. S. Murray, Chem. Sci., 2013, 4, 1719
DOI: 10.1039/C3SC22300K

Social activity

Search articles by author

Spotlight

Advertisements