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Issue 6, 2013
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Redox of ferrocene controlled asymmetric dehydrogenative Heck reactionviapalladium-catalyzed dual C–H bond activation

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Abstract

A novel strategy of dehydrogenative Heck reaction controlled by redox process of ferrocene has been developed. Commercially available chiral amino acid as ligand realized asymmetric dehydrogenative Heck reaction, leading to planar-chiral ferrocene derivatives with excellent enantioselectivity and in good to excellent yields (up to 99% ee and 98% yield).

Graphical abstract: Redox of ferrocene controlled asymmetric dehydrogenative Heck reaction via palladium-catalyzed dual C–H bond activation

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Supplementary files

Article information


Submitted
28 Feb 2013
Accepted
08 Apr 2013
First published
09 Apr 2013

Chem. Sci., 2013,4, 2675-2679
Article type
Edge Article

Redox of ferrocene controlled asymmetric dehydrogenative Heck reaction via palladium-catalyzed dual C–H bond activation

C. Pi, Y. Li, X. Cui, H. Zhang, Y. Han and Y. Wu, Chem. Sci., 2013, 4, 2675
DOI: 10.1039/C3SC50577D

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