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Issue 42, 2013
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Additive-free solvothermal synthesis of hierarchical flower-like LiFePO4/C mesocrystal and its electrochemical performance

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Abstract

Three dimensional hierarchical flower-like lithium iron phosphate (LiFePO4) mesocrystals were successfully synthesized via a solvothermal approach with the utilization of a mixture of water/ethylene glycol/dimethylacetamide (H2O/EG/DMAC) as co-solvent. No other surfactant or template agent was used and beautiful micro-sized LiFePO4 mesoporous structures with a special rose-like morphology were obtained. The hierarchical LiFePO4 mesocrystals were assembled by well crystallized nano-sized LiFePO4 thin plates with a thickness around 100 nm. The characteristics and electrochemical dynamics as well as performance of the obtained hierarchical flower-like LiFePO4 mesocrystals were carefully investigated. The flower-like hierarchical LiFePO4 mesocrystals showed a high initial lithium intercalation capability of 147 mA h g−1 at a current density of 17 mA g−1 (0.1 C), which should be attributed to the high specific surface area resulting from the mesoporous superstructure and well crystallized LiFePO4 nano-plate composition units. Polyvinylpyrrolidone (PVP) was introduced during the solvothermal synthesis as an in situ carbon coating source. The obtained flower-like C-coated LiFePO4 mesocrystals exhibited even better initial lithium intercalation capability of 161 mA h g−1 at 0.1 C and showed improved lithium storage performance at high rates as well as good cyclic stability.

Graphical abstract: Additive-free solvothermal synthesis of hierarchical flower-like LiFePO4/C mesocrystal and its electrochemical performance

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Article information


Submitted
08 Jun 2013
Accepted
12 Aug 2013
First published
06 Sep 2013

RSC Adv., 2013,3, 19366-19374
Article type
Paper

Additive-free solvothermal synthesis of hierarchical flower-like LiFePO4/C mesocrystal and its electrochemical performance

N. Zhou, E. Uchaker, H. Wang, M. Zhang, S. Liu, Y. Liu, X. Wu, G. Cao and H. Li, RSC Adv., 2013, 3, 19366
DOI: 10.1039/C3RA42855A

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