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Issue 25, 2013
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Selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over intercalated vanadium phosphate oxides

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Abstract

The selective oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) was studied over vanadium phosphate oxide (VPO)-based heterogeneous catalysts in the liquid phase. The selectivity to DFF was highly increased when using intercalated vanadium phosphate oxides under mild conditions (1 atm of oxygen, 110 °C) in an aromatic solvent. We found that the length of the intercalated ammonium alkyl chain had no clear influence on the catalytic performances, and a maximum yield of 83% could be achieved over C14VOPO4 and C14VOHPO4 after 6 h of reaction. Recycling of the catalyst was successfully performed, and we further obtained some insights in the reaction pathway: while the desired oxidation reaction indeed proceeded over the catalyst, the formation of by-products was linked to the presence of free radicals in solution.

Graphical abstract: Selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over intercalated vanadium phosphate oxides

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Supplementary files

Article information


Submitted
18 Feb 2013
Accepted
25 Apr 2013
First published
26 Apr 2013

RSC Adv., 2013,3, 9942-9948
Article type
Paper

Selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over intercalated vanadium phosphate oxides

F. L. Grasset, B. Katryniok, S. Paul, V. Nardello-Rataj, M. Pera-Titus, J. Clacens, F. De Campo and F. Dumeignil, RSC Adv., 2013, 3, 9942
DOI: 10.1039/C3RA41890A

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