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Issue 13, 2013
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Capture of benzotriazole-based Mannich electrophiles by CH-acidic compounds

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Abstract

The Mannich-type capture reaction of aminoalkylbenzotriazoles by CH acidic compounds is documented. The pKa of the benzotriazole counteranion is key to the success of such reactions, whereas the global electrophilicity of the reactive iminium moiety is secondary.

Graphical abstract: Capture of benzotriazole-based Mannich electrophiles by CH-acidic compounds

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Supplementary files

Article information


Submitted
08 Nov 2012
Accepted
14 Jan 2013
First published
16 Jan 2013

RSC Adv., 2013,3, 4152-4155
Article type
Communication

Capture of benzotriazole-based Mannich electrophiles by CH-acidic compounds

J. M. Monbaliu, L. K. Beagle, F. K. Hansen, C. V. Stevens, C. McArdle and A. R. Katritzky, RSC Adv., 2013, 3, 4152
DOI: 10.1039/C3RA22826F

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