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Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications†

Massimo Benaglia,*a   Angelo Alberti,a   Loris Giorgini,b   Francesco Magnonia  and  Silvia Tozzia  
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* Corresponding authors

a Istituto per la Sintesi Organica e la Fotoreattività, Consiglio Nazionale delle Ricerche, Area della Ricerca, via P. Gobetti, 101, 40129 Bologna, Italy
E-mail: massimo.benaglia@cnr.it

b Dipartimento di Chimica Industriale e dei Materiali, Facoltà di Chimica Industriale, Università di Bologna, Viale del Risorgimento, 4, 40136 Bologna, Italy

Abstract

The treatment of poly(glycidyl methacrylate) with nucleophilic agents yielded new linear homo/co-polymers. The materials obtained have different physicochemical properties depending upon the nucleophiles utilized and thus, by this way, water soluble polymers are easily accessible. This approach is also very convenient for the synthesis of amphiphilic block copolymers. Additional chemical modifications can further transform the obtained polymers after the post-polymerization treatment. Starting from RAFT pre-synthesized/pre-functionalized polymers, the described procedures allow us to obtain a wide variety of chemically diverse materials characterized by controlled structure and specific functions.

Graphical abstract: Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications

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Article information

https://doi.org/10.1039/C2PY20646C
Submitted
13 Aug 2012
Accepted
10 Sep 2012
First published
12 Sep 2012
Polym. Chem., 2013,4, 124-132
Article type
Paper
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Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications

M. Benaglia, A. Alberti, L. Giorgini, F. Magnoni and S. Tozzi, Polym. Chem., 2013, 4, 124
DOI: 10.1039/C2PY20646C

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