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Issue 12, 2013
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Asymmetric organic/metal(oxide) hybrid nanoparticles: synthesis and applications

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Abstract

Asymmetric particles (APs) with broken centrosymmetry are of great interest, due to the asymmetric surface properties and diverse functionalities. In particular, organic/metal(oxide) APs naturally combine the significantly different and complementary properties of organic and inorganic species, leading to their unique applications in various fields. In this review article, we highlighted recent advances in the synthesis and applications of organic/metal(oxide) APs. This type of APs is grounded on chemical or physical interactions between metal(oxide) NPs and organic small molecular or polymeric ligands. The synthetic methodologies were summarized in three categories, including the selective surface modifications, phase separation of mixed ligands on the surface of metal(oxide) NPs, and direct synthesis of APs. We further discussed the unique applications of organic/metal(oxide) APs in self-assembly, sensors, catalysis, and biomedicine, as a result of the distinctions between asymmetrically distributed organic and inorganic components. Finally, challenges and future directions are discussed in an outlook section.

Graphical abstract: Asymmetric organic/metal(oxide) hybrid nanoparticles: synthesis and applications

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Article information


Submitted
10 Dec 2012
Accepted
21 Jan 2013
First published
24 Jan 2013

Nanoscale, 2013,5, 5151-5166
Article type
Review Article

Asymmetric organic/metal(oxide) hybrid nanoparticles: synthesis and applications

J. He, Y. Liu, T. C. Hood, P. Zhang, J. Gong and Z. Nie, Nanoscale, 2013, 5, 5151
DOI: 10.1039/C3NR34014G

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