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Issue 13, 2013
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Primary and tertiary amines bifunctional graphene oxide for cooperative catalysis

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Abstract

In this study, primary and tertiary amine bifunctional graphene oxide (GO–NH2–NEt2) was prepared by silylanization of graphene oxide (GO) with amine-terminal silanes. The obtained GO–NH2–NEt2 was characterized by infrared spectrum (FTIR), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Systematic studies demonstrated the GO–NH2–NEt2 had excellent catalytic activities and 100% selectivity in the classic trans-β-nitrostyrene forming reaction.

Graphical abstract: Primary and tertiary amines bifunctional graphene oxide for cooperative catalysis

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Publication details

The article was received on 18 Mar 2013, accepted on 17 Apr 2013 and first published on 23 Apr 2013


Article type: Paper
DOI: 10.1039/C3NR01323E
Nanoscale, 2013,5, 6030-6033

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    Primary and tertiary amines bifunctional graphene oxide for cooperative catalysis

    W. Zhang, S. Wang, J. Ji, Y. Li, G. Zhang, F. Zhang and X. Fan, Nanoscale, 2013, 5, 6030
    DOI: 10.1039/C3NR01323E

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