Covering: 1993 to 2002
The synthesis of eribulin mesylate from microgram to multi-gram scale is described in this Highlight. Key coupling reactions include formation of the C30a to C1 carbon–carbon bond and macrocyclic ring closure through an intramolecular Nozaki–Hiyama–Kishi reaction.
M. J. Yu, W. Zheng and B. M. Seletsky, Nat. Prod. Rep., 2013, 30, 1158 DOI: 10.1039/C3NP70051H
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