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Issue 38, 2013
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Sumanenylferrocenes and their solid state self-assembly

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Abstract

The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

Graphical abstract: Sumanenylferrocenes and their solid state self-assembly

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Publication details

The article was received on 13 Jun 2013, accepted on 09 Aug 2013 and first published on 12 Aug 2013


Article type: Communication
DOI: 10.1039/C3DT51569A
Dalton Trans., 2013,42, 13809-13812

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    Sumanenylferrocenes and their solid state self-assembly

    B. Topolinski, B. M. Schmidt, S. Higashibayashi, H. Sakurai and D. Lentz, Dalton Trans., 2013, 42, 13809
    DOI: 10.1039/C3DT51569A

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