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Issue 28, 2013
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Dehydrogenative desulfurization of thiourea derivatives to give carbodiimides, using hydrosilane and an iron complex

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Abstract

Dehydrogenative desulfurization of thiourea derivatives (RNHC(S)NHR′) has been achieved, to give carbodiimides (RN[double bond, length as m-dash]C[double bond, length as m-dash]NR′), in the reaction with hydrosilane and (η5-C5H5)Fe(CO)2Me. The obtained carbodiimide reacted with (η5-C5H5)Fe(CO)(SiR3) formed in the reaction to give an N-silylated η2-amidino iron complex, which was isolated and then characterized by X-ray analysis.

Graphical abstract: Dehydrogenative desulfurization of thiourea derivatives to give carbodiimides, using hydrosilane and an iron complex

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Publication details

The article was received on 16 Apr 2013, accepted on 08 May 2013 and first published on 10 May 2013


Article type: Paper
DOI: 10.1039/C3DT50996F
Dalton Trans., 2013,42, 10271-10276

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    Dehydrogenative desulfurization of thiourea derivatives to give carbodiimides, using hydrosilane and an iron complex

    K. Hayasaka, K. Fukumoto and H. Nakazawa, Dalton Trans., 2013, 42, 10271
    DOI: 10.1039/C3DT50996F

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