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Issue 21, 2013
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A novel single-site manganese(ii) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water

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Abstract

A novel single site Mn(II) complex was successfully synthesized and tested in the aqueous disproportionation of hydrogen peroxide. The complex was found to be stable (HR-XAS) and exhibits catalase-like activity in neutral pH. Theoretical calculations suggested a reaction mechanism involving two complexes, changes in metal oxidation state and proton shuttling.

Graphical abstract: A novel single-site manganese(ii) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water

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Article information


Submitted
28 Jan 2013
Accepted
18 Mar 2013
First published
18 Mar 2013

Dalton Trans., 2013,42, 7761-7767
Article type
Paper

A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water

M. Zienkiewicz, J. Szlachetko, C. Lothschütz, M. Hodorowicz, A. Jabłońska-Wawrzycka, J. Sá and B. Barszcz, Dalton Trans., 2013, 42, 7761
DOI: 10.1039/C3DT50288K

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