Issue 6, 2013
From the journal:

Dalton Transactions

The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−†

Fei Xu,a   Kazuhiko Matsumoto*a  and  Rika Hagiwaraa  

* Corresponding authors

a Graduate School of Energy Science, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: k-matsumoto@energy.kyoto-u.ac.jp
Fax: +81 75-753-5906
Tel: +81 75-753-4817

Abstract

The first example of a face-sharing fluoroaluminate anion, Al2F93−, is crystallographically determined in [C18MIm]3[Al2F9](CH2Cl2)1.754 (C18MIm+ = 1-methyl-3-octadecylimidazolium cation), and the geometry and bond properties therein are discussed with the aid of quantum chemical calculations.

Graphical abstract: The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−

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Article information

DOI
https://doi.org/10.1039/C2DT32624H
Article type
Communication
Submitted
02 Nov 2012
Accepted
30 Nov 2012
First published
30 Nov 2012

Dalton Trans., 2013,42, 1965-1968

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The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−

F. Xu, K. Matsumoto and R. Hagiwara, Dalton Trans., 2013, 42, 1965 DOI: 10.1039/C2DT32624H

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